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21.
The relationship between the magmatism of the Cretaceous Ofuku pluton and mineralization in and around the Akiyoshi Plateau, Yamaguchi Prefecture, Japan was investigated using a combination of field observation, petrographic and geochemical analyses, K–Ar geochronology, and fluid inclusion data. The Ofuku pluton has a surface area of 1.5 × 1.0 km, and was intruded into the Paleozoic accretionary complexes of the Akiyoshi Limestone, Ota Group and Tsunemori Formation in the western part of the Akiyoshi Plateau. The pluton belongs to the ilmenite‐series and is zoned, consisting mainly of early tonalite and granodiorite that share a gradational contact, and later granite and aplite that intruded the tonalite and granodiorite. Harker diagrams show that the Ofuku pluton has intermediate to silicic compositions ranging from 60.4 to 77.9 wt.% SiO2, but a compositional gap exists between 70.5 to 73.4 wt.% SiO2 (anhydrous basis). Modal and chemical variations indicate that the assumed parental magma is tonalitic. Quantitative models of fractional crystallization based on mass balance calculations and the Rayleigh fractionation model using major and trace element data for all crystalline phases indicate that magmatic fractionation was controlled mainly by crystal fractionation of plagioclase, hornblende, clinopyroxene and orthopyroxene at the early stage, and quartz, plagioclase, biotite, hornblende, apatite, ilmenite and zircon at the later stage. The residual melt extracted from the granodiorite mush was subsequently intruded into the northern and western parts of the Ofuku pluton as melt lens to form the granite and aplite. The age of the pluton was estimated at 99–97 Ma and 101–98 Ma based on K–Ar dating of hornblende and biotite, respectively. Both ages are consistent within analytical error, indicating that the Ofuku pluton and the associated Yamato mine belong to the Tungsten Province of the San‐yo Belt, which is genetically related to the ilmenite‐series granitoids of the Kanmon to Shunan stages. The aplite contains Cl‐rich apatite and REE‐rich monazite‐(Ce), allanite‐(Ce), xenotime and bastnäsite‐(Ce), indicating that the residual melt was rich in halogens and REEs. The tonalite–granodiorite of the Ofuku pluton contains many three‐phase fluid inclusions, along with daughter minerals such as NaCl and KCl, and vapor/liquid (V/L) volume ratios range from 0.2 to 0.9, suggesting that the fluid was boiling. In contrast, the granite and aplite contain low salinity two‐phase inclusions with low V/L ratios. The granodiorite occupies a large part of the pluton, and the inclusions with various V/L ratios with chloride daughter minerals suggest the boiling fluids might be related to the mineralization. This fluid could have carried base metals such as Cu and Zn, forming Cu ore deposits in and around the Ofuku pluton. The occurrence and composition of fluid inclusions in the igneous rocks from the Akiyoshi Plateau are directly linked to Cu mineralization in the area, demonstrating that fluid inclusions are useful indicators of mineralization.  相似文献   
22.
New high-pressure orthorhombic (GdFeO3-type) perovskite polymorphs of MnSnO3 and FeTiO3 have been observed using in situ powder X-ray diffraction in a diamond-anvil cell with synchrotron radiation. The materials are produced by the compression of the lithium niobate polymorphs of MnSnO3 and FeTiO3 at room temperature. The lithium niobate to perovskite transition occurs reversibly at 7 GPa in MnSnO3, with a volume change of -1.5%, and at 16 GPa in FeTiO3, with a volume change of -2.8%. Both transitions show hysteresis at room temperature. For MnSnO3 perovskite at 7.35 (8) GPa, the orthorhombic cell parameters are a=5.301 (2) A, b=5.445 (2) Å, c=7.690 (8) Å and V= 221.99 (15) Å3. Volume compression data were collected between 7 and 20 GPa. The bulk modulus calculated from the compression data is 257 (18) GPa in this pressure region. For FeTiO3 perovskite at 18.0 (5) GPa, cell parameters are a=5.022 (6) Å, b=5.169 (5) Å, c=7.239 (9) Å and V= 187.94 (36) Å3. Based on published data on the quench phases, the FeTiO3 perovskite breaks down to a rocksalt + baddelyite mixture of FeO and TiO2 at 23 GPa. This is the first experimental verification of the pressure-induced breakdown of a perovskite to simple oxides.  相似文献   
23.
To better understand the variation of water quality in the Mekong River, sampling and measurement were scheduled twice a week for about 3 years at Vientiane, followed by basic statistical analysis of the observed data. The frequent measurement revealed detailed characteristics of the water quality variation, which had not been detected by monthly observation in the previous studies. The variation in total ionic content was considered to be governed by dilution of the amount of water. Increases in turbidity could be attributed to physical effects including surface soil erosion and bed material resuspension at the time of discharge increase. Nitrogen concentrations were stably low during the low flow period and abruptly increased in May. After the annual maximum in late May, the nitrate concentration steadily decreased regardless of the remarkable rise in the discharge from mid‐July, whereas the ammonium concentration remained at a similar level until October. It was considered that the first small discernable runoff after the long dry season flushed the accumulated nitrogen in the surface soil and mobilized the nitrogen in the riverbed. The variation in phosphorus concentrations was different from that in nitrogen concentrations. During the high flow period, continual dilutions at discharge peaks and occasional large additions of phosphorus by surface runoff were suggested. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
24.
25.
Ongoing geological research into processes operating on the nearshore continental shelf and beyond is vital to our understanding of modern tsunami-generated sediment transport and deposition. This paper investigates the southern part of Sendai Bay, Japan, by means of high-resolution seismic surveys, vibracoring, bathymetric data assimilation, and radioisotope analysis of a core. For the first time, it was possible to identify an erosional surface in the shallow subsurface, formed by both seafloor erosion and associated offshore-directed sediment transport caused by the 2011 Tohoku-oki tsunami. The area of erosion and deposition extends at least 1,100 m offshore from the shoreline down to water depths of 16.7 m. The tsunami-generated sedimentological signature reaches up to 1.2 m below the present seafloor, whereas bathymetric changes due to storm-related reworking over a period of 3 years following the tsunami event have been limited to the upper ~0.3 m, despite the fact that the study area is located on an open shelf facing the Pacific Ocean. Tsunami-generated erosion surfaces may thus be preserved for extended periods of time, and may even enter the rock record, because the depth of tsunami erosion can exceed the depth of storm erosion. This finding is also important for interpretation of modern submarine strata, since erosion surfaces in shallow (depths less than ~1 m) seismic records from open coast shelves have generally been interpreted as storm-generated surfaces or transgressive ravinement surfaces.  相似文献   
26.
Toru Takeshita  Koshi Yagi 《Island Arc》2001,10(3-4):495-505
Abstract The orientations of both healed extension microcracks and microcracks in quartz grains sealed mostly by carbonate minerals were measured from Cretaceous granodiorite core samples drilled along the Nojima Fault, southwest Japan. The preferred orientations of both healed and sealed microcracks consist of approximately three orthogonal sets, (components) A, B and C, in which A strikes NS–NW-SE and dips vertically, B strikes EW–NE-SW and dips vertically, and C is subhorizontal. Both the healed and sealed microcracks were possibly formed by hydraulic fracturing, and the successive release of tensile stress due to pore fluid overpressure in the principal stress directions could have caused this microcracking in mutually orthogonal directions. The quartz grains are also very moderately plastically deformed, which is indicated by the occurrence of kink bands and undulose extinction. The association of healed microcracks and kink bands in the quartz suggests that these microstructures formed under subgreenschist facies conditions (≈300°C) during hydrothermal activity that could have occurred immediately after the emplacement of granodiorite during the Late Cretaceous period. Based on both the preferred orientation of microcracks, and c-axis fabrics of kinked and unkinked grains (so called kink method), it is inferred that the σ1-and σ3-axis were oriented horizontally in NS–NW-SE and EW–NE-SW directions, respectively. The inferred paleostress field does not conform to the east–west-trending compression during the Quaternary period, but to the activation of EW–NE-SW-trending, left–lateral strike–slip faults during the Late Cretaceous period in southwest Japan.  相似文献   
27.
The process of crystallization and the origin of chondrules are discussed, in terms of the phase relations of the minerals in chondrules in six ordinary chondrites of the Yamato-74 meteorites, especially the Yamato-74191 (L3).Chondrules are classified into six types. The bulk compositions of chondrules projected onto the MgO-FeO-SiO2 system show that the compositions of chondrules vary widely. Investigations by means of the MgO-Al2O3-SiO2 system indicate that porphyritic chondrules can be regarded as products of supercooling crystallization. The growth rates of crystals in porphyritic chondrules were fairly small. The difference between types of chondrules is interpreted in terms of the compositions of chondrules and the nucleation temperatures of the supercooled droplets.All these observations and estimations must be taken into account for discussing the origin of chondrules. The impact and dust fusion theories do not appear to be plausible. Molten droplets due to these mechanisms will be glassy spherules, or crystallize at equilibrium. Only a liquid condensation theory can well explain the characteristic features and the process of the crystallization of chondrules.  相似文献   
28.
Synthetic diopsides in the join CaMgSi2O6 CaCrAlSiO6 have been studied by means of crystal-field theory. These diopsides are either blue or pale green in colour. The former forms at lower temperatures and the latter at higher temperatures. The optical spectra and colours can be unequivocally explained based on the assumption that Cr3+ions occupy both tetrahedral and octahedral sites in the diopsides. In the blue diopsides Cr3+ions are present in two kinds of spin state, i.e., tetrahedrally coordinated low spin and octahedrally coordinated high spin. On heating the blue diopsides, tetrahedral occupancy of chromium decreases sharply due to spin transformation from tetrahedral low spin to octahedral high spin. Above 1,160° C nearly all chromium ions are present in octahedral sites with high spin state and the diopsides become pale green in colour. Some petrogenetic applications of the resultes are discussed.  相似文献   
29.
A mixture containing equal amounts of forsterite and grossularite by weight (Fo50Gr50) has been studied at temperatures between 750 and 1400°C under pressures ranging from 6 to 25 kbar in presence of excess water. The assemblages noted under low pressure (<8 kbar) are as follows: Diopsidess+forsteritess+monticellitess+vapor and Diopsidess+forsteritess+monticellitess+liquid+vapor. (ss denotes solid solution) Under intermediate pressures between 8 and 24 kbar following assemblages were noted in the order of increasing temperature: Diopsidess+forsteritess+spinel+vapor, Diopsidess+forsteritess+spinel+liquid+vapor, Diopsidess+forsteritess+liquid+vapor, and Forsteritess+liquid+vapor. At pressures above 24 kbar the assemblages are as follows: Diopsidess+forsteritess+garnet+vapor, Diopsidess+forsteritess+garnet+liquid+vapor, Diopsidess+forsteritess+liquid+vapor, and Forsteritess+liquid+vapor. Electron microprobe analyses of diopside and forsterite crystallized at 1050°C and 23 kbar, show that the former contains 6 to 6.5 wt % of Al2O3 as solid solution whereas the latter incorporates 1.3 wt % of monticellite in solid solution. The monticellite content of forsterite increases at low pressures at a given temperature to about 6 wt % at 1050°C and 6 kbar. The study indicates that forsteritic olivine does not coexist with pure grossularite in the studied temperature and pressure ranges, although the former is in equilibrium with pyrope-rich garnet, containing 23 mole % grossularite. The study supports the conclusion ofWerner andLuth (1973) that the solubility of monticellite in forsterite decreases with increasing pressure at a given temperature. The results of the investigation are also in agreement with the findings ofKushiro andYoder (1966), who noted that spinel peridotites found in folded belts and in alkalic basalts are produced under intermediate pressures, whereas garnet peridotite xenoliths found in kimberlite and in orogenic belts are formed at high pressures.  相似文献   
30.
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